USGS - science for a changing world

South Dakota Water Science Center

orange dotHome orange dotScience Topics orange dotOur Cooperators orange dotPublications orange dotGIS/Geospatial Resources orange dotNewsroom orange dotOutreach orange dotContact

DATA CENTER

INFORMATION CENTER

USGS IN YOUR STATE

USGS Water Science Centers are located in each state.

There is a USGS Water Science Center office in each State. Washington Oregon California Idaho Nevada Montana Wyoming Utah Colorado Arizona New Mexico North Dakota South Dakota Nebraska Kansas Oklahoma Texas Minnesota Iowa Missouri Arkansas Louisiana Wisconsin Illinois Mississippi Michigan Indiana Ohio Kentucky Tennessee Alabama Pennsylvania West Virginia Georgia Florida Caribbean Alaska Hawaii New York Vermont New Hampshire Maine Massachusetts South Carolina North Carolina Rhode Island Virginia Connecticut New Jersey Maryland-Delaware-D.C.

U.S. Geological Survey
Water-Resources Investigations Report 02-4079
Online Version 1.0

A National Survey of Methyl tert-Butyl Ether and Other Volatile Organic Compounds in Drinking-Water Sources: Results of the Random Survey

By Stephen J. Grady

Methyl tert-butyl ether (MTBE) was detected in source water used by 8.7 percent of randomly selected community water systems (CWSs) in the United States at concentrations that ranged from 0.2 to 20 micrograms per liter (µg/L). The Random Survey conducted by the U.S. Geological Survey, in cooperation with the Metropolitan Water District of Southern California and the Oregon Health & Science University, was designed to provide an assessment of the frequency of detection, concentration, and distribution of MTBE, three other ether gasoline oxygenates, and 62 other volatile organic compounds (VOCs) in ground- and surface-water sources used for drinking-water supplies. The Random Survey was the first of two components of a national assessment of the quality of source water supplying CWSs sponsored by the American Water Works Association Research Foundation. A total of 954 CWSs were selected for VOC sampling from the population of nearly 47,000 active, self-supplied CWSs in all 50 States, Native American Lands, and Puerto Rico based on a statistical design that stratified on CWS size (population served), type of source water (ground and surface water), and geographic distribution (State).

At a reporting level of 0.2 µg/L, VOCs were detected in 27 percent of source-water samples collected from May 3, 1999 through October 23, 2000. Chloroform (in 13 percent of samples) was the most frequently detected of 42 VOCs present in the source-water samples, followed by MTBE. VOC concentrations were generally less than 10 g/L—95 percent of the 530 detections—and 63 percent were less than 1.0 µg/L. Concentrations of 1,1-dichloroethene, tetrachloroethene, trichloroethene, vinyl chloride, and total trihalomethanes (TTHMs), however, exceeded drinking-water regulations in eight samples.

Detections of most VOCs were more frequent in surface-water sources than in ground-water sources, with gasoline compounds collectively and MTBE individually detected significantly more often in surface water. Use of personal and commercial motorized watercraft on surface-water bodies that are drinking-water sources is probably the reason for the elevated detections of gasoline contaminants relative to ground water. MTBE detections demonstrated a seasonal pattern with more frequent detections in surface water in summer months, which is consistent with seasonal watercraft use.

The detection frequency of most VOCs was significantly related to urban land use and population density. Detections of any VOC, non-trihalomethane compounds, gasoline compounds collectively, the specific gasoline compounds benzene, toluene, ethylbenzene, and xylenes (BTEX), MTBE, solvents, and refrigerants were significantly greater in areas with more than 60 percent urban land use and (or) population density greater than 1,000 people per square mile than in source waters from less urbanized or lower population-density areas. MTBE detections were five times more frequent in source waters from areas with high MTBE use than in source waters from low or no MTBE use, but, unlike other gasoline compounds, MTBE detections were not significantly related to the density of gasoline storage tanks near drinking-water sources.

Download a PDF version of the report [9.43 MB]

Download Adobe Acrobat Reader for free

Accessibility and Adobe

USGS Home Water Climate Change Core Science Ecosystems Energy and Minerals Env. Health Hazards

Accessibility FOIA Privacy Policies and Notices

Take Pride in America logo USA.gov logo U.S. Department of the Interior | U.S. Geological Survey
URL: http://sd.water.usgs.gov/nawqa/pubs/wrir/wrir02_4079.html
Page Contact Information: Webmaster
Page Last Modified: Wednesday, 09-Jan-2013 10:50:31 EST